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CAS Number: 3140-73-6. Molecular Weight: 175.57. Beilstein/REAXYS Number: 148988. EC Number: 221-541-0. MDL number: MFCD00075607. PubChem Substance ID: 24863373. NACRES: NA.22. 375217-5G. $63.70. Availability. Available to ship on May 15, 2024 Details. Add to Cart. Request a Bulk Order.
2-Chlor-4,6-dimethoxy-1,3,5-triazin 97%; CAS Number: 3140-73-6; EC Number: 221-541-0; find Sigma-Aldrich-375217 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich.
CDMT is a reagent which has been used mainly in SPPS. In the presence of N-methylmorpholine (NMM) as base, the reagent gives low levels of racemization. Numerous oligopeptides of 3-heteroaryloamino-2,3-dehydroalanine have been obtained using CDMTas the coupling reagent.
9 ott 2006 · Markowicz and Dembinski developed a fluorous 2-chloro-4,6-bis-[(heptadecafluorononyl)oxy]-1,3,5-triazine (F CDMT), an analog of CDMT, as a new coupling reagent in peptide synthesis. 107 It was prepared from CC and heptadecafluorononan-1-ol (Scheme 21), and fully characterized.
27 mar 2013 · CDMT is known to react with tertiary amines such as 4-methylmorpholine and N,N-dimethylglycine esters to form triazinylammonium salts that act as dehydrocondensing reagents such as 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride (DMT-MM). 5 As these reactions complete within 30 min at room temperature, 6 the ...
1 apr 2012 · CDMT (116) is a cheap reagent which has been used mainly in SPPS. In the presence of N -methylmorpholine (NMM) as base, the reagent gives low levels of racemization (<4.2%). It has also been used for the coupling of hindered amino acids ( Kamiński, 1987 , Kamiński, 1994 ).
20 dic 2014 · In summary, CDMT is an efficient and convenient reagent for the one-pot synthesis of 2-azetidinones from imines and carboxylic acids under mild conditions. Simple aqueous workup removes the byproduct of CDMT and any resulting salts.
